Title

The Synthesis and Characterization of uns-cisDicyano-1, I O-Diamino-4, 7-Diazadecane Cobalt(III) Chloride

Document Type

Article

Publication Date

1981

Publication Source

Inorganica Chimica Acta

Abstract

As part of our investigation of complexes of the type Co(tetramine)Lt+, we report the synthesis and characterization of uns-cis Co(3,2,3-tet)(CN)+2 (3,2,3-tet is the flexible tetramine ligand 1 JO-diamino4,7-diazadecane). This is the first reported diacido cobalt(III) complex with this polyamine which adopts the uns-cis stereochemistry. Other uns-cis cobalt complexes of 3,2,3-tet are known only when a bidentate chelating ligand occupies two coordination sites on the cobalt ion.

Inclusive pages

L233-L234

ISBN/ISSN

0020-1693

Publisher

Elsevier

Volume

53

Peer Reviewed

yes