Title
Symmetrical Ring Cleavage of the Gold(I) Phosphorus Ylide Dimer [Au(CH2)2PPh2]2 by Hydrogen Halides in Toluene
Document Type
Article
Publication Date
1-1987
Publication Source
Inorganica Chimica Acta
Abstract
The reaction of the cyclic, 8-membered gold(I) ylide dimer, bis [μ-(dimethylenediphenylphosphoranyl-C,C)]-digold(I), [Au(CH2)2PPh2]2, with two moles of HX (X = Cl, Br) in toluene yields the symmetric cleavage product halo(methylmethylenediphenylphosphoranyl)-gold(I), XAuCH2PPh2- (CH3), as the only isolable gold containing product. Further addition of HX affords a dimethyldiphenylphosphonium dihaloaurate(I) salt.
Inclusive pages
7-10
ISBN/ISSN
0020-1693
Copyright
Copyright © 1987, Elsevier.
Publisher
Elsevier
Volume
126
Peer Reviewed
yes
Issue
1
eCommons Citation
Knachel, Howard; Dettorre, Colleen A.; Galaska, Henry J.; Salupo, Teresa A.; Frackler, John P. Jr.; and Murray, H. H., "Symmetrical Ring Cleavage of the Gold(I) Phosphorus Ylide Dimer [Au(CH2)2PPh2]2 by Hydrogen Halides in Toluene" (1987). Chemistry Faculty Publications. 53.
https://ecommons.udayton.edu/chm_fac_pub/53
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