Title
Preparation of Phosphonoterephthalic Acids via Palladium-catalyzed Coupling of Aromatic Iodoesters
Document Type
Article
Publication Date
2013
Publication Source
Synthetic Communications
Abstract
The current article reports in detail the preparation of two phosphonoterephthalic acids: 2-phosphonoterephthalic acid (1) and 2,5-diphosphonoterephthalic acid (2). Efficient, scalable syntheses have been developed for both compounds based on Pd-catalyzed coupling reactions of iodinated terephthalate esters. Phosphonoterephthalic acids are potentially useful as flame-retardant additives or as monomers for the construction of acid-pendant polymer chains.
Inclusive pages
1831-1836
ISBN/ISSN
0039-7911
Document Version
Postprint
Copyright
Copyright © 2013, Taylor & Francis
Publisher
Taylor & Francis
Volume
43
Peer Reviewed
yes
Issue
13
eCommons Citation
Ivan, Nathaniel; Benin, Vladimir; and Morgan, Alexander, "Preparation of Phosphonoterephthalic Acids via Palladium-catalyzed Coupling of Aromatic Iodoesters" (2013). Chemistry Faculty Publications. 6.
https://ecommons.udayton.edu/chm_fac_pub/6
Included in
Analytical Chemistry Commons, Biochemical Phenomena, Metabolism, and Nutrition Commons, Chemical and Pharmacologic Phenomena Commons, Environmental Chemistry Commons, Inorganic Chemistry Commons, Materials Chemistry Commons, Medical Biochemistry Commons, Medicinal-Pharmaceutical Chemistry Commons, Organic Chemistry Commons, Other Chemistry Commons, Physical Chemistry Commons
Comments
The document available for download is the authors' accepted manuscript, posted here in compliance with the publisher's policy on self-archiving. Some differences may exist between this version and the publisher's version; as such, researchers wishing to quote directly from it are advised to consult the version of record, available at many libraries or from the publisher: http://dx.doi.org/10.1080/00397911.2012.673448
Permission documentation is on file.