Carbon-13 Nuclear Magnetic Resonance Studies of Trans-Diacido(tetraamine) Cobalt(III) Complexes
Document Type
Article
Publication Date
6-1982
Publication Source
Inorganic Chemistry
Abstract
Carbon-1 3 nuclear magnetic resonance spectra of a series of trans-diacido( 1 ,lO-diamino-4,7-dia~aadecane)cobalt(III) complexes (truns-Co(3,2,3-tet)X2, X = Br-, C1-, N3-, NH,, NO2-, OAc) and trans-diacido( 1,9-diamino-3,7-diazanonane)cobalt(III) complexes (trans-Co(2,3,2-tet)X2, X = C1-, GlyH, -OAc, NH,, NO2-) will be discussed. The "C chemical shift is found to be linearly dependent on the ligand field strength (estimated from the electronic spectrum) of the axial ligands (X). The shielding of selected carbon atoms within the tetraamine ligand, which has been attributed to the central metal ion, increases with increasing axial ligand field strength.
Inclusive pages
2223–2226
ISBN/ISSN
0020-1669
Publisher
American Chemical Society
Volume
21
Peer Reviewed
yes
Issue
6
eCommons Citation
Brubaker, George R. and Johnson, David W., "Carbon-13 Nuclear Magnetic Resonance Studies of Trans-Diacido(tetraamine) Cobalt(III) Complexes" (1982). Chemistry Faculty Publications. 22.
https://ecommons.udayton.edu/chm_fac_pub/22
