"Synthesis of Some Copper(II) Complexes with Ligands Derived from the S" by David W. Johnson and Helen K. Mayer
 

Synthesis of Some Copper(II) Complexes with Ligands Derived from the Schiff Base Reaction Between 2-Pyridinecarboxaldehyde and Aliphatic Amines

Document Type

Article

Publication Date

1-1987

Publication Source

Inorganica Chimica Acta

Abstract

As part of our continuing investigations of the influence of stereochemical demands of ligands on the spectroscopy of transition metal complexes [1], we have prepared a series of copper(H) complexes with ligands derived from the Schiff base reaction of 2-pyridinecarboxaldehyde or 6-methyl-2-pyridinecarboxaldehyde and various aliphatic amines [2]. These imine complexes are structurally similar to some dicopper(II) complexes which have interesting optical and magnetic properties [3]. The complexes, differing only in steric bulk, are a systematic method of studying the effects of the steric bulk of the ligand on the spectroscopy of the copper(H) complex.

Inclusive pages

L1-L2

ISBN/ISSN

0020-1693

Publisher

Elsevier

Volume

126

Peer Reviewed

yes

Issue

1


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