Synthesis of Rhodium(III), Iridium(III) and Osmium(III) Complexes with tris(2-Aminoethane-thiolato)cobalt(III)

Author(s)

David W. Johnson, University of DaytonFollow
Timothy R. Brewer, University of Dayton

Document Type

Article

Publication Date

12-1988

Publication Source

Inorganica Chimica Acta

Abstract

Polynuclear sulfur bridged complexes where the neutral complex tris(2-aminoethanethiolato)cobalt(III) acts as a tridentate ligand to rhodium(III), iridium(III) and osmium(III) have been prepared. These complexes have been characterized by electronic spectroscopy, vibrational spectroscopy and nuclear magnetic resonance spectroscopy. Along with the previously prepared complexes of iron(III), ruthenium(III) and cobalt(III), these complexes form two series of complexes with the group 8 and group 9 elements from all three transition series.

Inclusive pages

221-224

ISBN/ISSN

0020-1693

Comments

The authors wish to thank the University of Dayton Research Council for their support in the form of a summer fellowship for David W. Johnson and assistance in the purchase of equipment used in this study. The authors also wish to acknowledge partial support from the Ohio Board of Regents Challenge Grant program for the purchase of the NMR instrument used in this study.

Publisher

Elsevier

Volume

154

Peer Reviewed

yes

Issue

2

eCommons Citation

Johnson, David W. and Brewer, Timothy R., "Synthesis of Rhodium(III), Iridium(III) and Osmium(III) Complexes with tris(2-Aminoethane-thiolato)cobalt(III)" (1988). Chemistry Faculty Publications. 34.
https://ecommons.udayton.edu/chm_fac_pub/34