Addition Compounds of Phosphorus(V) Chloride and Aromatic Nitrogen Bases. Crystal Structure and 1H NMR and Raman Spectra of Pyrazine-Phosphorus(V) Chloride

Author(s)

J. N. Ishley, University of Dayton
Howard Knachel, University of DaytonFollow

Document Type

Article

Publication Date

1975

Publication Source

Inorganic Chemistry

Abstract

It has been established that the compound of empirical formula Pels exhibits three coordination numbers dependent upon the physical state and choice of solvent. Two competing equilibria have recently been reported1 in ionizing solvents

2PC1, == PC1,' + PCI,- PCI, t PCl,+ + C1-

In the solid state, a metastable crystal modification has been found and proposed2 to incorporate chloride ions into the crystal lattice which would normally contain only PCh+ ions and PCbions.

Inclusive pages

2558–2560

ISBN/ISSN

0020-1669

Comments

The authors wish to thank the University of Dayton Research Council for the funds used in establishing the laboratory. Registry No. Pyrazine.PCl₅, 55975-46-7.

Publisher

American Chemical Society

Volume

14

Peer Reviewed

yes

Issue

10

eCommons Citation

Ishley, J. N. and Knachel, Howard, "Addition Compounds of Phosphorus(V) Chloride and Aromatic Nitrogen Bases. Crystal Structure and 1H NMR and Raman Spectra of Pyrazine-Phosphorus(V) Chloride" (1975). Chemistry Faculty Publications. 47.
https://ecommons.udayton.edu/chm_fac_pub/47