Title
Activation of Two Carbon-Hydrogen Bonds of Nitromethane by a Dinuclear Gold(II) Ylide Complex. The Formation of a CHNO2-Bridged A-Frame Complex
Document Type
Article
Publication Date
1984
Publication Source
Organometallics
Abstract
The reaction of CH,NO, (neat) with the dinuclear gold(II) ylide complex Au2[(CH2)2PPh2]2(O2CPh)2 leads to the rupture of two C-H bonds and the formation of an A-frame species with a CHNO2 bridge. The X-ray molecular structure and the 500-MHz solution 1H NMR spectrum establish the formation of the species.
Inclusive pages
1312–1313
ISBN/ISSN
0276-7333
Publisher
American Chemical Society
Volume
3
Peer Reviewed
yes
Issue
8
eCommons Citation
Knachel, Howard; Dudis, Douglas; and Frackler, John P. Jr., "Activation of Two Carbon-Hydrogen Bonds of Nitromethane by a Dinuclear Gold(II) Ylide Complex. The Formation of a CHNO2-Bridged A-Frame Complex" (1984). Chemistry Faculty Publications. 48.
https://ecommons.udayton.edu/chm_fac_pub/48
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